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Pyrolysis of burning material, especially incomplete combustion or smoldering without adequate oxygen supply, also results in production of a large amount of hydrocarbons, both aliphatic and aromatic , I don’t smoke weed to escape reality i smoke it to enjoy reality even more shirt terpenes. Heterocyclic compounds may be also present. Heavier hydrocarbons may condense as tar; smoke with significant tar content is yellow to brown. Presence of such smoke, soot, and/or brown oily deposits during a fire indicates a possible hazardous situation, as the atmosphere may be saturated with combustible pyrolysis products with concentration above the upper flammability limit, and sudden inrush of air can cause flashover or backdraft.
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Hydrogen fluoride can be formed from fluorocarbons, whether fluoropolymers subjected to fire or halocarbon fire suppression agents. Phosphorus and antimony oxides and their reaction products can be formed from some fire retardant additives, increasing smoke toxicity and corrosivity. Pyrolysis of polychlorinated biphenyls , e.g. from burning older transformer oil, and to lower degree also of other chlorine-containing materials, can produce 2,3,7,8-tetrachlorodibenzodioxin, a potent carcinogen, and other polychlorinated dibenzodioxins. Pyrolysis of fluoropolymers, e.g. teflon, in presence of oxygen yields carbonyl fluoride ; other compounds may be formed as well, e.g. carbon tetrafluoride, hexafluoropropylene, and highly toxic perfluoroisobutene
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